Stephen Garoff
Professor, Physics

Education
Ph.D., Harvard UniversityResearch
The properties of interfacial regions where fluid or solid phases meet dominate the behavior of many natural and technical processes. Wetting, friction and adhesion, corrosion, stability of emulsions (droplets of liquids in another liquid) or colloidal suspensions (solid particles suspended in a liquid) are some examples. But attaining a fundamental understanding of their behavior challenges our experimental abilities because these interfacial regions are structurally complex on a molecular scale, are seldom homogeneous on a microscopic scale, and may not even be in equilibrium. Often monomolecular layers along the interfaces dominate the behavior of the interface and the macroscopic phenomenon. In the Interfacial Physics Group we attempt to build an understanding of interfacial phenomena on the molecular, microscopic, and macroscopic levels. In our research, we probe many different liquid systems, including aqueous and non-aqueous fluids and solutions, surfactants and polymers, and even metals interacting with a variety of solids, including glasses, oxides and metals. We employ a range of techniques including x-ray, neutron, and optical techniques, atomic force microscopy, rheology, as well as UHV and non-UHV materials preparation. Presently, we focus on wetting, friction, and colloidal forces. Our program draws on a broad range of scientific phenomena such as random field effects, nonequilibrium states, hydrodynamics, and noise in hysteretic systems. The results of our research reveal the scientific underpinnings of such technologies as coatings, adhesion, colloidal stability, and multiphase fluid flow.
We maintain extensive collaborations with groups in the Material Science, Chemical Engineering an Biomedical Engineering Departments at Carnegie Mellon as well as in the University of Pittsburgh Medical School. We participate in the programs of the Center for Complex Fluids Engineering. We also work on applications of our research through projects funded by industry. For more details on our group, see Interfacial Physics Group.
Selected Publications
- Ramankur Sharma, Roomi Kalita, Ellen R. Swanson, Timothy E. Corcoran, Stephen Garoff, Todd M. Przybycien, Robert D. Tilton, Autophobing on Liquid Subphases Driven by the Interfacial Transport of Amphiphilic Molecules, Langmuir 28, 15212 (2012)
- R.T. Cerbus, S. Garoff, W.I. Goldburg, E.R. Peterson, Local heating at convection fronts and moving contact lines on hygroscopic fluids, Colloids and Surfaces A: Physicochemical and Engineering Aspects 393, 42 (2012)
- P. R. Harvey, R. Tarran, S. Garoff, M. M. Myerburg, Measurement of the Airway Surface Liquid Volume with Simple Light Refraction Microscopy, American Journal of Respiratory Cell and Molecular Biology 45, 592 (2011)
- Kevin Koch, Beautia Dew, Timothy E. Corcoran, Todd M. Przybycien, Robert D. Tilton, Stephen Garoff, Surface Tension Gradient Driven Spreading on Aqueous Mucin Solutions: A Possible Route to Enhanced Pulmonary Drug Delivery, Molecular Pharmaceutics 8, 387 (2011)
- Satyajeet Ojha, Benjamin Beppler, Hongchen Dong, Krzysztof Matyjaszewski, Stephen Garoff, Michael R. Bockstaller, Impact of Polymer Graft Characteristics and Evaporation Rate on the Formation of 2-D Nanoparticle Assemblies, Langmuir 26, 13210 (2010)
- Y Wei, E Rame, L M Walker, S Garoff, Dynamic wetting with viscous Newtonian and non-Newtonian fluids, Journal of Physics: Condensed Matter 21, 464126 (2009)
- Amy L. Marcinkowski, Stephen Garoff, Robert D. Tilton, Joseph M. Pilewski, Timothy E. Corcoran, Postdeposition Dispersion of Aerosol Medications Using Surfactant Carriers, Journal of Aerosol Medicine and Pulmonary Drug Delivery 21, 361 (2008)
- Benjamin K. Beppler, Kalyani S. Varanasi, Stephen Garoff, Guennadi Evmenenko, Kristina Woods, Influence of Fluid Flow on the Deposition of Soluble Surfactants Through Receding Contact Lines of Volatile Solvents, Langmuir 24, 6705 (2008)
- P. Wynblatt, D. Chatain, A. Ranguis, J. P. Monchoux, J. Moon, S. Garoff, Factors Affecting the Coverage Dependence of the Diffusivity of One Metal over the Surface of Another, International Journal of Thermophysics 28, 646 (2007)
- Junhyung Kim, Stephen Garoff, John L. Anderson, Luc J. M. Schlangen, Movement of Colloidal Particles in Two-Dimensional Electric Fields, Langmuir 21, 10941 (2005)
- H. Burnett, T. Shedd, G. Nellis, M. El-Morsi, R. Engelstad, S. Garoff, K. Varanasi, Control of the receding meniscus in immersion lithography, Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures 23, 2611 (2005)
- R. T. Schumacher, S. Garoff, J. Woodhouse, Probing the Physics of Slip–Stick Friction using a Bowed String, The Journal of Adhesion 81, 723 (2005)
- Jaehyun Moon, Paul Wynblatt, Stephen Garoff, Robert Suter, Diffusion kinetics of Bi and Pb–Bi monolayer precursing films on Cu(111), Surface Science 559, 149 (2004)
- B. Luokkala, S. Garoff, R. Suter, Using x-ray reflectivity to determine the structure of surfactant monolayers, Physical Review E 62, 2405 (2000)
- John L. Anderson, Darrell Velegol, Stephen Garoff, Measuring Colloidal Forces Using Differential Electrophoresis, Langmuir 16, 3372 (2000)
