Published in Phys. Rev. B 91, 205408 (2015).
Oxygen Vacancies on SrO-terminated SrTiO3(100) Surfaces studied by Scanning Tunneling Spectroscopy
Wattaka Sitaputra,1 Nikhil Sivadas,2 Marek Skowronski,1 Di Xiao,2 Randall M. Feenstra2
1Department of Materials Science and Engineering, Carnegie Mellon University, Pittsburgh, PA 15213
2Department of Physics, Carnegie Mellon University, Pittsburgh, PA 15213
Abstract
The electronic structure of SrTiO3(001) surfaces was studied using scanning tunneling spectroscopy and density-functional theory. With high dynamic range measurements, an in-gap transition level was observed on SrO-terminated surfaces, at 2.7 eV above the valence band maximum. The density of centers responsible for this level was found to increase with surface segregation of oxygen vacancies and decrease with exposure to molecular oxygen. Based on these finding, the level is attributed to surface O vacancies. A level at a similar energy is predicted theoretically on SrO-terminated surfaces. For TiO2-terminated surfaces, no discrete mid-gap state was observed, although one is predicted theoretically. This lack of signal is believed to be due to the nature of defect wavefunction involved, as well as the possible influence of transport limitations in the STS measurements.
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